Quantum-well states in a double-well system: an example of Cu/Co(Ni)/Cu.

The quantum-well (QW) states in the Cu/Co double-well system are studied by first-principles calculations. We have shown that the monolayer Ni or Co as a heterogeneous spacer in Cu QW can not only disturb the QW states extending into the whole structure, but also create new QW states because of the interfaces introduced, resulting in sub-well-confining electrons. If the QW state energy in two sub-wells is close to each other, these two sub-well QW states can couple together. We have also demonstrated that monolayer Co and Ni spacers play different roles for modulating QW states at different energy levels, which also result in a complicated distribution of QW states. The obtained results are in good agreement with experiment data.